During the Rooftop Battle on Onigashima, Luffy figures out Kaido's secret after taking a devastating hit. He realizes that Kaido coats his club with Supreme King Haki. Luffy replicates the technique, infusing his fists with the energy. This allows him to strike Kaido without making physical contact, dealing massive damage to the Emperor for the first time. Episode 1046: Splitting the Sky
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| Haki Status | Anime Episode | Scene / Description | Key Significance | | :--- | :--- | :--- | :--- | | | Episode 389 | While fighting Duval, Luffy knocks out Motobaro the bison. | His very first, unnamed flare-up of the power. | | Unconscious Use | Episode 413 | During his battle on Amazon Lily, Luffy knocks out many Kuja warriors. | First time it's referred to by its name in the story. | | Awakening / Unconscious | Episode 479 (Key Episode) | At Marineford, Luffy's Haki prevents Ace's execution, saving his life. | The most crucial moment; his will becomes a power that changes the world. | | Intentional Use | Episode 649 | Luffy clashes Haki with Don Chinjao in the Colosseum. | Proves he has conscious control after his training with Rayleigh. | | Intentional Use | Episode 723 | Luffy engages in a powerful Supreme King Haki clash with Doflamingo. | Visually stunning display of Haki as a direct offensive weapon. | | Intentional Use | Episode 1028 | Luffy learns to apply Supreme King Haki to his attacks while fighting Kaido. | A game-changing moment; he learns the advanced application needed to fight Emperors. | | Peak Intentional Use | Episode 1071 | In Gear 5, Luffy emits an island-shaking burst of Supreme King Haki. | Shows his peak mastery, combining his awakened Devil Fruit with his Haki. | During the Rooftop Battle on Onigashima, Luffy figures
Luffy consciously (but unknowingly) uses it on Amazon Lily after Marigold and Sandersonia threaten to destroy the broken portrait of Fisher Tiger. This allows him to strike Kaido without making
Luffy replicates his Marineford feat to save the Vinsmoke family. He screams at the top of his lungs to destroy the portrait of Mother Carmel, releasing a burst of Haki that disrupts Big Mom's tea party and helps trigger her mental breakdown. Episode 869: The Katakuri Clash (Whole Cake Island Arc)
Ace is on the execution platform, and the executioners raise their blades to end his life. In a desperate, primal scream to stop them, Luffy unleashes a massive wave of Supreme King Haki.